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- W2015331212 abstract "Abstract An efficient ligand design strategy towards boosting asymmetric induction was proposed, which simply employed inorganic nanosheets to modify α‐amino acids and has been demonstrated to be effective in vanadium‐catalyzed epoxidation of allylic alcohols. Here, the strategy was first extended to zinc‐catalyzed asymmetric aldol reaction, a versatile bottom‐up route to make complex functional compounds. Zinc, the second‐most abundant transition metal in humans, is an environment‐friendly catalytic center. The strategy was then further proved valid for organocatalyzed metal‐free asymmetric catalysis, that is, α‐amino acid catalyzed asymmetric aldol reaction. Visible improvement of enantioselectivity was experimentally achieved irrespective of whether the nanosheet‐attached α‐amino acids were applied as chiral ligands together with catalytic Zn II centers or as chiral catalysts alone. The layered double hydroxide nanosheet was clearly found by theoretical calculations to boost ee through both steric and H‐bonding effects; this resembles the role of a huge and rigid substituent." @default.
- W2015331212 created "2016-06-24" @default.
- W2015331212 creator A5022452954 @default.
- W2015331212 creator A5023673759 @default.
- W2015331212 creator A5040271009 @default.
- W2015331212 creator A5047131675 @default.
- W2015331212 date "2012-10-16" @default.
- W2015331212 modified "2023-10-18" @default.
- W2015331212 title "Nanosheet-Enhanced Asymmetric Induction of Chiral α-Amino Acids in Catalytic Aldol Reaction" @default.
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