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- W2015340295 abstract "Cyclic voltammetry and electrochemical impedance spectroscopy were used to study the surface acid-base property of carboxylic acid-terminated self-assembled monolayers (SAMs). A carboxylic acid-terminated thiol, such as thioctic acid (l,2-dithiolane-3-pentanoic acid), was self-assembled on gold electrodes. Electron transfer between the bulk solution and the SAM modified electrode was studied at different pH using Fe(CN)63− as a probe. The surface pKa. of thioctic acid was determined by cyclic voltammetry and electrochemical impedance spectroscopy to be 5.6 ± 0.1 and 5.8 ± 0.1, respectively. The method is compared with other methods of monolayer pKa measurement." @default.
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- W2015340295 date "2010-08-27" @default.
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- W2015340295 title "Study on surface acid-base property of carboxylic acid-terminated self-assembled monolayers by cyclic voltammetry and electrochemical impedance spectroscopy" @default.
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- W2015340295 doi "https://doi.org/10.1002/cjoc.20000180612" @default.
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