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- W2015340557 abstract "Abstract A series of metal complexes have been prepared using two similar ketiminato ligands, ArL1H (([RN(H)(C(Me))2C(Me) O], ((R = 2,6-diisopropylphenyl (Dipp) or 2,6-dimethylphenyl, (Dmp)) and the less bulky, multidentate molecule L2H, ([RN(H)C(Me)CHC(Me) O] (R = C2H4NEt2)). Reaction of ArL1H or ArL1Na with Co(SCN)2, Eu(OTf)3 and Cu(OTf)2, afforded [Co(DippL1H)2(NCS)2] (1), [Eu(DippL1H)3(OTf)3] (2), and [Cu(OTf)2(DippL1H)2] (3). The coordination preferences of ArL1 and L2 with FeBr2 were investigated and yielded crystals of [Fe(DippL1)2] (4), [L2FeBr·LiBr(THF)2] (5), and [{(DmpN C(Me))2C(H)Me}FeBr2] (6). Complexes 1–6 have been structurally characterized by X-ray crystallography, and other pertinent techniques." @default.
- W2015340557 created "2016-06-24" @default.
- W2015340557 creator A5060268699 @default.
- W2015340557 creator A5085085833 @default.
- W2015340557 date "2010-06-01" @default.
- W2015340557 modified "2023-09-23" @default.
- W2015340557 title "Ketiminato and ketimine Co, Eu, Cu and Fe complexes" @default.
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- W2015340557 doi "https://doi.org/10.1016/j.ica.2010.02.019" @default.
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