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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015358308> ?p ?o ?g. }

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• W2015358308 abstract "N,N-Dimethylcarbamoylation of the anilinic nitrogen atom N(1) on the spiro 7-azaindoline consists of two steps. The first step is N,N-dimethylcarbamoylation of the pyridyl nitrogen atom N(7), leading to the formation of an isolable intermediate. The second step is intermolecular migration of the N,N-dimethylcarbamoyl group from the pyridyl nitrogen atom N(7) to the anilinic nitrogen atom N(1). We accomplished optimization of the reaction conditions based on the revealed reaction mechanism and a large scale synthesis of compound 3 in quantitative yield." @default.
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• W2015358308 date "2013-11-01" @default.
• W2015358308 modified "2023-09-25" @default.
• W2015358308 title "Experimental and computational study of intermolecular migration of N,N-dimethylcarbamoyl group from N(7) to N(1) on a 7-azaindoline derivative" @default.
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• W2015358308 doi "https://doi.org/10.1016/j.tet.2013.09.024" @default.
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