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- W2015366507 abstract "A new catalytic reaction is proposed and a kinetic method developed for the determination of ultramicro amounts of Cu(II) on the basis of its catalytic activity in oxidation of the 2-thiosemicarbazone of sodium 1,2-naphthoquinone-4-sulphonate by hydrogen peroxide in the presence of ascorbic acid. Under optimal conditions the sensitivity of the method is 0.25 ng/ml. The relative error is 4.8-18.2% for the concentration range 5-0.8 ng/ml. Most foreign ions do not change the rate of the catalysed reaction. Co(2+) and I(-) catalyse the reaction, Ni(2+) extensively inhibits it, and in the presence of EDTA only the uncatalysed reaction takes place." @default.
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- W2015366507 date "1980-04-01" @default.
- W2015366507 modified "2023-09-25" @default.
- W2015366507 title "Kinetic determination of ultramicro amounts of copper" @default.
- W2015366507 doi "https://doi.org/10.1016/0039-9140(80)80096-8" @default.
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