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- W2015366988 abstract "Abstract The substituted titanocene dicarbonyl complexes, Cp2Ti(CO)2, CpCp∗Ti(CO)2, 1Cp∗2Ti(CO)2 and CpCpCF3Ti(CO)2, were reacted with chloroform, yielding the respective titanocene dichloride complexes. The electronic effects of the substituents on the cyclopentadienyl ligands were evaluated by infrared spectroscopy and by X-ray photoelectron spectroscopy (XPS). Pseudo first order rate constants were then determined for each of the substituted titanocene dicarbonyl complexes as they reacted with chloroform. No correlation between these electronic effects and the rate constants was possible, however, since the rate constants remained essentially identical regardless of the substituents on the cyclopentadienyl ligands. The reaction of Cp2Ti(CO)2 with chloroform was also evaluated under normal conditions and exhibited overall first order kinetics, although the rate constant was affected by the chloroform concentration. This suggests a preequilibrium dissociated and reassociation of a carbonyl ligand in the first step in the reaction. Therefore, rather than exhibiting a lack of substituent effects, the rate constants may reflect an adjustment of the preequilibrium position caused by opposing electronic and steric effects imposed by the substituted cyclopentadienyl ligands." @default.
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- W2015366988 date "1995-05-01" @default.
- W2015366988 modified "2023-09-26" @default.
- W2015366988 title "SUBSTITUENT EFFECTS ON OXIDATIVE ADDITION TO TITANOCENE DICARBONYL COMPLEXES" @default.
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- W2015366988 doi "https://doi.org/10.1080/00958979508033084" @default.
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