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• W2015370609 abstract "Reciprocal donor acceptor selectivity (RDAS) and double diastereodifferentiation are two concepts that have been used to explain how a glycosyl acceptor and donor may be ‘matched’ or ‘mismatched’ in glycosylation reactions. We describe here how the α-l-fucosylation and β-d-galactosylation of a trisaccharide displaying two equatorial OH groups at C-3 of N-acylated glucosamine units led to different regioselectivities or different ‘matched’ pairs. These results may be explained under the reciprocal donor acceptor selectivity or double diastereodifferentiation concepts. We also suggest a third explanation to these results: the presence of a benzylidene at the nonreducing end acceptor led to rigidity at this residue which resulted into a mismatched pair during β-d-galactosylation but allowed α-l-fucosylation." @default.
• W2015370609 created "2016-06-24" @default.
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• W2015370609 date "2012-08-01" @default.
• W2015370609 modified "2023-09-23" @default.
• W2015370609 title "Matched and mismatched acceptor/donor pairs in the glycosylation of a trisaccharide diol free at O-3 of two N-acylated glucosamine residues" @default.
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• W2015370609 doi "https://doi.org/10.1016/j.carres.2012.04.020" @default.
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