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• W2015371341 abstract "Abstract The intrinsic viscosity [η] of cellulose acetate (CA) has been determined in two solvents: acetic acid (AA) and N,N-dimethylacetamide (DMAC). The samples of this cellulose derivative have a rather weak mean molecular weight MW, with a mean degree of polymerization DP ranging from 213 to 47 and the same origin. We use the theory of Yamakawa for a worm-like chain to obtain the hydrodynamic diameter D and the persistence length q for these samples of CA, and the Mark-Houwink equation to estimate the parameters K and α. These results were compared with the same parameters obtained with previous experimental published results for CA with a high MW. The measurements were also carried out at different temperatures; the intrinsic-viscosity temperature dependence is discussed. The D and q values calculated for the low-MW range allow estimation of the critical concentrations C* for the solutions, which are compared with experimental results." @default.
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• W2015371341 date "1989-12-01" @default.
• W2015371341 modified "2023-09-23" @default.
• W2015371341 title "Mesophase formation and intrinsic viscosity for some low-molecular-weight cellulose acetate samples" @default.
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• W2015371341 doi "https://doi.org/10.1080/02678298908045681" @default.
• W2015371341 hasPublicationYear "1989" @default.
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