Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015372743> ?p ?o ?g. }
- W2015372743 endingPage "3253" @default.
- W2015372743 startingPage "3247" @default.
- W2015372743 abstract "Abstract Attempts to identify the intermediates and/or active species generated from binary combinations of a lanthanide alk(aryl)oxide with a dialkylmagnesium reagent, which behave as efficient olefin polymerization systems, are reported. The well‐defined trinuclear complex [Nd 3 (μ 3 ‐O t Bu) 2 (μ 2 ‐O t Bu) 3 (μ‐O t Bu) 4 (THF) 2 ] ( 1 ) and the monomeric precursor [Nd(OC 6 H 2 t Bu 2 ‐2,6‐Me‐4) 3 (THF)] ( 2 ) were used in association with [Mg(CH 2 SiMe 3 ) 2 (Et 2 O)] ( 3 ). The new heterodimetallic complex [(THF)Nd(μ 3 ‐O t Bu) 2 (μ 2 ‐O t Bu) 2 (O t Bu)Mg 2 (CH 2 TMS) 2 ] ( 4 ) and the alkyllanthanide complex [Nd(OC 6 H 2 t Bu 2 ‐2,6‐Me‐4) 2 (CH 2 SiMe 3 )(THF) 2 ] ( 5 ) have been isolated and characterized in the solid state and in solution. Complex 4 is proposed to be a reaction intermediate in the active species formation, while complex 5 is the first alkyllanthanide species isolated from an “Ln(OR) 3 ”/MgR 2 mixture, consistent with the observed behavior of these combinations in olefin polymerization. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
- W2015372743 created "2016-06-24" @default.
- W2015372743 creator A5005637283 @default.
- W2015372743 creator A5007328859 @default.
- W2015372743 creator A5015617876 @default.
- W2015372743 creator A5043010780 @default.
- W2015372743 creator A5064611725 @default.
- W2015372743 creator A5069335597 @default.
- W2015372743 date "2004-08-01" @default.
- W2015372743 modified "2023-09-25" @default.
- W2015372743 title "Binary Neodymium Alkoxide/Dialkylmagnesium Polymerization Systems: Studies on the Nature of the Reaction Intermediates and Active Species" @default.
- W2015372743 cites W1608129452 @default.
- W2015372743 cites W1967410320 @default.
- W2015372743 cites W1967984957 @default.
- W2015372743 cites W1976981788 @default.
- W2015372743 cites W1982613000 @default.
- W2015372743 cites W1983254551 @default.
- W2015372743 cites W1990518101 @default.
- W2015372743 cites W1991457726 @default.
- W2015372743 cites W2027562297 @default.
- W2015372743 cites W2034491652 @default.
- W2015372743 cites W2036161907 @default.
- W2015372743 cites W2041480994 @default.
- W2015372743 cites W2045922196 @default.
- W2015372743 cites W2046266901 @default.
- W2015372743 cites W2050843794 @default.
- W2015372743 cites W2051217784 @default.
- W2015372743 cites W2053610446 @default.
- W2015372743 cites W2054952049 @default.
- W2015372743 cites W2055584482 @default.
- W2015372743 cites W2061234578 @default.
- W2015372743 cites W2074731395 @default.
- W2015372743 cites W2076179647 @default.
- W2015372743 cites W2078972240 @default.
- W2015372743 cites W2081610230 @default.
- W2015372743 cites W2083387355 @default.
- W2015372743 cites W2087847610 @default.
- W2015372743 cites W2089391154 @default.
- W2015372743 cites W2089718695 @default.
- W2015372743 cites W2104720744 @default.
- W2015372743 cites W2111283164 @default.
- W2015372743 cites W2167590372 @default.
- W2015372743 cites W223761024 @default.
- W2015372743 cites W2951141724 @default.
- W2015372743 cites W4236891489 @default.
- W2015372743 doi "https://doi.org/10.1002/ejic.200400036" @default.
- W2015372743 hasPublicationYear "2004" @default.
- W2015372743 type Work @default.
- W2015372743 sameAs 2015372743 @default.
- W2015372743 citedByCount "18" @default.
- W2015372743 countsByYear W20153727432013 @default.
- W2015372743 countsByYear W20153727432022 @default.
- W2015372743 crossrefType "journal-article" @default.
- W2015372743 hasAuthorship W2015372743A5005637283 @default.
- W2015372743 hasAuthorship W2015372743A5007328859 @default.
- W2015372743 hasAuthorship W2015372743A5015617876 @default.
- W2015372743 hasAuthorship W2015372743A5043010780 @default.
- W2015372743 hasAuthorship W2015372743A5064611725 @default.
- W2015372743 hasAuthorship W2015372743A5069335597 @default.
- W2015372743 hasConcept C120665830 @default.
- W2015372743 hasConcept C121332964 @default.
- W2015372743 hasConcept C145148216 @default.
- W2015372743 hasConcept C155647269 @default.
- W2015372743 hasConcept C161790260 @default.
- W2015372743 hasConcept C166940927 @default.
- W2015372743 hasConcept C178790620 @default.
- W2015372743 hasConcept C185592680 @default.
- W2015372743 hasConcept C201770740 @default.
- W2015372743 hasConcept C2778839380 @default.
- W2015372743 hasConcept C40875361 @default.
- W2015372743 hasConcept C44228677 @default.
- W2015372743 hasConcept C51886252 @default.
- W2015372743 hasConcept C520434653 @default.
- W2015372743 hasConcept C521977710 @default.
- W2015372743 hasConcept C540262125 @default.
- W2015372743 hasConcept C71240020 @default.
- W2015372743 hasConceptScore W2015372743C120665830 @default.
- W2015372743 hasConceptScore W2015372743C121332964 @default.
- W2015372743 hasConceptScore W2015372743C145148216 @default.
- W2015372743 hasConceptScore W2015372743C155647269 @default.
- W2015372743 hasConceptScore W2015372743C161790260 @default.
- W2015372743 hasConceptScore W2015372743C166940927 @default.
- W2015372743 hasConceptScore W2015372743C178790620 @default.
- W2015372743 hasConceptScore W2015372743C185592680 @default.
- W2015372743 hasConceptScore W2015372743C201770740 @default.
- W2015372743 hasConceptScore W2015372743C2778839380 @default.
- W2015372743 hasConceptScore W2015372743C40875361 @default.
- W2015372743 hasConceptScore W2015372743C44228677 @default.
- W2015372743 hasConceptScore W2015372743C51886252 @default.
- W2015372743 hasConceptScore W2015372743C520434653 @default.
- W2015372743 hasConceptScore W2015372743C521977710 @default.
- W2015372743 hasConceptScore W2015372743C540262125 @default.
- W2015372743 hasConceptScore W2015372743C71240020 @default.
- W2015372743 hasIssue "16" @default.
- W2015372743 hasLocation W20153727431 @default.
- W2015372743 hasOpenAccess W2015372743 @default.
- W2015372743 hasPrimaryLocation W20153727431 @default.
- W2015372743 hasRelatedWork W1499438900 @default.