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• W2015391650 abstract "Abstract The thermal decomposition reaction of N,N'-thioamines to produce azo-derivatives and sulfur, considering thionitroso derivatives (R[sbnd]N[dbnd]S) as intermediates, was investigated using AM1 and Ab-Initio M.O. calculations. Thermodynamic arguments indicate an endothermic formation of the thionitroso species, but a favoured exothermic decomposition to products. Molecular and electronic structure, for the proposed intermediate four member cyclic molecule of sulfur and nitrogen (R2N2S2), in the transformation of R[sbnd]N[dbnd]S to R[sbnd]N[dbnd]N[sbnd]R and sulfur, were obtained. Estimation of kinetic parameters for the formation and decomposition of this structure, confirm the intermediate nature of it." @default.
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• W2015391650 date "1995-05-01" @default.
• W2015391650 modified "2023-10-14" @default.
• W2015391650 title "GENERATION OF THIONITROSO COMPOUNDS FROM N,N'-THIODIAMINES. A MOLECULAR ORBITAL STUDY" @default.
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• W2015391650 doi "https://doi.org/10.1080/10426509508042539" @default.
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