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- W2015392754 abstract "(−)-Malyngolide (1a) and its three stereomers 1b–d are synthesized from the allylic alcohol 4 in total yields of about 10% each. The key reaction steps are Sharpless epoxidation of the allylic alcohol 4 and radical CC bond formation with the iodide 3 and methyl methacrylate (2). This radical chain reaction needs only small amounts of organotin compounds. Totalsynthese von (−)-Malyngolid und seinen drei Stereomeren (−)-Malyngolid (1a) und seine drei Stereomeren 1b–d werden aus dem Allylalkohol 4 in jeweils 10% Gesamtausbeute synthetisiert. Schlüsselstufen der Synthese sind die Sharpless-Epoxidierung des Allylalkohols 4 und die radikalische CC-Bindungsbildung mit dem Iodid 3 und Methacrylsäure-methylester (2). Diese radikalische CC-Bindungsbildung benötigt nur geringe Mengen an Organozinnverbindungen." @default.
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- W2015392754 date "1987-03-24" @default.
- W2015392754 modified "2023-10-09" @default.
- W2015392754 title "Total Synthesis of (−)-Malyngolide and of Its Three Stereomers" @default.
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- W2015392754 doi "https://doi.org/10.1002/jlac.198719870313" @default.
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