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• W2015392810 abstract "The preparation of new palladium complexes that are composed of a series of chiral dipyridylphosphines [(R)-P-Phos (1), (R)-tol-P-Phos (2) and (R)-Xyl-P-Phos) (3)] have been described. The structure of the complex [{(R)-1}Pd(H2O)2](OTf)2 was unambiguously determined by single-crystal X-ray diffractometry. These complexes were found to be effective in the asymmetric bis-methoxycarbonylation of styrene, reaching up to 84% e.e. and 79% chemoselectivity for dimethyl-2-phenylsuccinate (DMPS) under the optimal conditions. In addition, the complexes exhibited almost identical enantioselectivity on DMPS." @default.
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• W2015392810 date "2003-04-01" @default.
• W2015392810 modified "2023-10-12" @default.
• W2015392810 title "Enantioselective bis-alkoxycarbonylation of styrene catalyzed by novel chiral dipyridylphosphine cationic palladium(II) complexes" @default.
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• W2015392810 doi "https://doi.org/10.1016/s1381-1169(02)00648-9" @default.
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