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• W2015396578 abstract "Abstract The ternary complexes (2,2′,2″-triaminotriethylamine)(ethylenediamine)nickel(II) perchlorate ( a ) and (2,2′,2″-triaminotriethylamine)(1,10-phenanthroline)nickel(II) perchlorate ( b ) have been synthesised by the reactions of (2,2′,2″-triaminotriethylamine)nickel(II) with ethylenediamine and 1,10-phenanthroline in EtOH–H 2 O mixture, respectively. The X-ray studies show that these complexes possess distorted octahedral geometry. The kinetic studies of ternary complex formation by stopped-flow method indicate that the reactions follow the pseudo first-order rate law and are reversible. The reaction with ethylenediamine was resolved into terms with formation rate constants k en  NiT =1.13×10 5 , k Hen  NiT =2.67×10 3 M −1 s −1 and dissociation rate constant k NiT(en) =3.5 s −1 . The rate-determining step in the en path is the ring closure whereas Hen + is the initial bond formation. The reaction involving phenanthroline was monitored with the formation rate constant k phen  NiT =1.30×10 4 M −1 s −1 and the dissociation rate constant k NiT(phen) =5.9 s −1 , and followed the Eigen–Tamm mechanism. The second NiN bond formation was the rate-determining step." @default.
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• W2015396578 date "2002-09-01" @default.
• W2015396578 modified "2023-09-22" @default.
• W2015396578 title "Synthesis, X-ray structures and ternary complex formation kinetics of (2,2′,2″-triaminotriethylamine)nickel(II) with bidentate ligands" @default.
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• W2015396578 doi "https://doi.org/10.1016/s0277-5387(02)01133-6" @default.
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