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- W2015398719 abstract "Abstract Novel films consist of multi-walled carbon nanotubes (MWCNT) were fabricated by means of catalytic chemical vapor deposition (CVD) technique with decomposition of either acetonitrile (ACN) or benzene (BZ) using ferrocene (FeCp2) as catalyst. The electrochemical and thermodynamic behavior of the ferrocyanide/ferricyanide, [Fe(CN)6]3−/4− redox couple on synthesized MWCNT-based films was investigated by means of cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques at T = (278.15, 283.15, 293.15, and 303.15) K. The redox couple [Fe(CN)6]3−/4− behaves quasi-reversibly on fabricated MWCNT-based films and its reversibility is enhanced upon increasing temperature. Namely, the findings establish that with the rise in temperature the barrier for interfacial electron transfer decreases, leading, consequently, to an enhancement of the kinetics of the charge transfer process. According to thermodynamics the equilibrium of the redox process is shifted towards the formation of [Fe(CN)6]3− at elevated temperatures." @default.
- W2015398719 created "2016-06-24" @default.
- W2015398719 creator A5004496551 @default.
- W2015398719 creator A5035977537 @default.
- W2015398719 date "2012-11-01" @default.
- W2015398719 modified "2023-10-14" @default.
- W2015398719 title "Electrochemical and thermodynamic properties of hexacyanoferrate(II)/(III) redox system on multi-walled carbon nanotubes" @default.
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- W2015398719 doi "https://doi.org/10.1016/j.jct.2012.03.018" @default.
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