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• W2015400519 abstract "Crystalline polymeric nanospheres composed of poly{stearyl methacrylate (SMA)-co-poly(ethylene glycol) monomethacrylate (PEGm)}s were prepared by the dispersion radical polymerization of SMA and PEGm in an ethanol/water solution. Scanning electron microscopy showed that the nanospheres were highly spherical, and had a narrow size distribution. Electron spectroscopy for chemical analysis and X-ray diffraction studies of the nanospheres suggested a core−corona-type structure; the hydrophilic PEGm corona accumulated on the nanosphere surface, while the hydrophobic SMA core formed a layered structure. Heat treatment caused a melting of the SMA layers, but successive cooling allowed it to re-form. Accompanying this reversible order−disorder transition, the nanospheres also showed a reversible aggregation/deaggregation behavior in their water-dispersion state." @default.
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• W2015400519 date "2005-09-02" @default.
• W2015400519 modified "2023-09-30" @default.
• W2015400519 title "Reversible Thermoresponsive Aggregation/Deaggregation of Water-Dispersed Polymeric Nanospheres Exhibiting Structural Transformation" @default.
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• W2015400519 doi "https://doi.org/10.1021/la050836l" @default.
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