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- W2015403763 abstract "The aqueous lithium–ion batteries using LiMn2O4 as cathode materials are considered to be one of the most promising stationary power sources for large-scale energy storage devices. In the present work, LiMn2O4 rods were successfully synthesized by using hydrothermal reaction to produce β-MnO2 rods as precursor followed by its solid-state lithiation. The influences of the solid-state reaction conditions on the final products were investigated and the electrochemical performances were tested in Li2SO4 aqueous electrolyte. The results show that LiMn2O4 rods can be obtained at 700 °C for 8 h (Sample A) and at 900 °C for 3 h (Sample B), respectively. Sample A exhibits superior electrochemical performances. The discharge capacities are 92.5, 92.9, 93.5 and 96.8 mAh g−1 at 1000, 500, 200 and 100 mA g−1, respectively. They are nearly constant between the high current density of 1000 and 200 mA g−1, demonstrating its high rate capability. In addition, sample A exhibits good cycling performance with only a total capacity loss of 5.4% after 200 cycles." @default.
- W2015403763 created "2016-06-24" @default.
- W2015403763 creator A5001720031 @default.
- W2015403763 creator A5027984932 @default.
- W2015403763 creator A5028270870 @default.
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- W2015403763 date "2013-12-01" @default.
- W2015403763 modified "2023-10-17" @default.
- W2015403763 title "LiMn2O4 rods as cathode materials with high rate capability and good cycling performance in aqueous electrolyte" @default.
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- W2015403763 doi "https://doi.org/10.1016/j.jallcom.2013.07.116" @default.
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