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- W2015403787 abstract "The buoyant titrations of poly-l-lysine and poly-l-histidine in CsCl, RbCl, CsBr, RbBr and KBr were measured. Large differences in buoyant densities measured at low pH were observed for both polymers. Densities in the alkali chloride solutions are lower than for the bromides and the buoyant density increases as the size of the cation decreases in the halide series. All buoyant densities converge to a common value for each polymer at high pH. These data are interpreted in terms of salt-pair formation at low pH and preferential hydrations were computed both for this charged species at low pH and for the neutral polymers at high pH. The resulting data were correlated with the water activity in each buoyant solution. The variation of hydration with water activity for the charged species is found to be similar to that previously reported for bovine serum mercaptalbumin while the hydrations of the neutral polymers are found to be nearly independent of water activity. Approximate observed ionization constants were determined for each polymer in four salt solutions." @default.
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- W2015403787 date "1978-03-01" @default.
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- W2015403787 title "Buoyant and potentiometric titrations of synthetic polypeptides III. Poly-l-lysine and poly-l-histidine in five salt solutions" @default.
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- W2015403787 doi "https://doi.org/10.1007/bf02906503" @default.
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