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- W2015403822 abstract "With a view to understanding the factors affecting the chemical properties of the copper sites in proteins, model copper(II) complexes of two multidentate ligands with nitrogen and sulfur atoms, 1,5-bis(2-pyridylmethylamino)-3-thiapentane (pmtp) and 2,6-bis(2,6-dithiaheptyl)pyridine (dthp), have been isolated as [Cu(pmtp)][Cu(pmtp)ClO4](ClO4)3 (1) and [Cu(dthp)(NO3)2] (2), respectively, and studied by X-ray diffraction, spectroscopic, and electrochemical methods. Complex 1 crystallizes in space group P21/a of the monoclinic system with four [Cu(pmtp)]2+ ions and four [Cu(pmtp)(ClO4)]+ ions in a cell of dimensions a = 24.180(7), b = 31.855(7), c = 9.760(3) A, and β = 143.84(1)°. The coordinations around the coppers in the two independent complexes are square-pyramidal and octahedral, respectively, with an amine nitrogen, two pyridine nitrogens, and a thioether sulfur at the equatorial positions (eq) and an amine nitrogen (and a perchlorate oxygen in addition in the octahedral complex) at the axial position..." @default.
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- W2015403822 title "Copper(II)-Thioether Bondings in Multidentate N,S-Donor Ligand Complexes. Structural Dependence of the Chemical Properties of the Copper(II) Complexes of 1,5-Bis(2-pyridylmethylamino)-3-thiapentane and 2,6-Bis(2,6-dithiaheptyl)pyridine" @default.
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- W2015403822 doi "https://doi.org/10.1246/bcsj.65.786" @default.
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