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- W2015404159 abstract "Abstract The role of potassium present on the surface or even built into the bulk has been studied in the chlorination of titanias by CCl 4 and COCl 4 to volatile TiCl 4 . The solids to be chlorinated were characterized by atomic absorption spectroscopy (AAS) and X-ray induced photoelectron spectroscopy (XPS) and the kinetics of the reaction was followed by thermogravimetry (TG). In case of COCl 2 a catalytic effect of potassium was observed whereas, when chlorinating with CCl 4 , potassium additives resulted in a strong retardation of the reaction. The results are interpreted in terms of the electronic structure of the solid surfaces and the different polarizability of the reactants." @default.
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- W2015404159 date "1987-01-01" @default.
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- W2015404159 title "On the role of potassium additives in the chlorination of TiO2 by CCl4 and COCl2" @default.
- W2015404159 doi "https://doi.org/10.1016/0042-207x(87)90101-1" @default.
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