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- W2015417229 abstract "The adsorption of benzene (Bz) on partial and full hydrogen and CO layers on W(110) indicates that H or CO block benzene chemisorption. The Bz vs. CO coverage curve shows two linear regimes, with different extrapolated maximum Bz coverages, suggesting that for CO/W>0.3 Bz is adsorbed (at least in part) tilted rather than flat on the surface. The adsorption of Bz on H/W(110) layers suggests that the effective blocking area of H atoms is 5×10−16 cm2, i.e. 0.69 of the area per W atom. Bz chemisorption decreases the work function by 1.5 eV at maximum coverage, 2.5×1014 molecules/cm2 on clean W(110). In the presence of CO |Δφ| values are smaller for the same Bz coverage than on clean W(110), suggesting electronic CO–Bz interaction. In the case of Bz/H/W(110) there is also a decrease in |Δφ| but only at high H coverages. Bz physisorption is different on saturated H/W(110) from that on saturated CO/W(110) layers. In the former case the various thermal desorption peaks seen for physisorbed Bz on chemisorbed Bz on W(110) or on O/W(110) are present, while on CO/W(110) the so-called α1 peak at 160 K is absent, indicating that physisorbed Bz is more weakly bound on CO0.7/W(110) than on clean or O covered W(110)." @default.
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- W2015417229 date "1999-06-01" @default.
- W2015417229 modified "2023-09-24" @default.
- W2015417229 title "The adsorption of benzene on H/W(110) and CO/W(110) layers" @default.
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- W2015417229 doi "https://doi.org/10.1016/s0039-6028(99)00288-5" @default.
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