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- W2015417360 abstract "An enamine intermediate in proline-catalyzed aldol reactions was indentified in situ by NMR studies on self-aldolization of aldehydes in DMSO. Only E-configured s-trans-enamines were detected in accordance with the generally accepted mechanism of enamine catalysis. The enamines were found to form directly from oxazolidinones (e.g., 3), and not via central iminium or iminium-like intermediates (e.g., 2) as evidenced by NMR exchange spectroscopy (EXSY). These results indicate a possible role of oxazolidinones in the catalytic cycle, beyond their involvement in ‘parasitic equilibria’." @default.
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- W2015417360 date "2010-07-22" @default.
- W2015417360 modified "2023-10-16" @default.
- W2015417360 title "NMR Detection of the Enamine Intermediate in Proline-Catalyzed Aldol Reactions" @default.
- W2015417360 doi "https://doi.org/10.1055/s-0030-1257809" @default.
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