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• W2015431489 abstract "The circular dichroism (CD) of the excited MLCT state of (Δ)-Ru(bpy)32+ was determined in the region from 260 to 400 nm using time-resolved circular dichroism (TRCD) spectroscopy with multichannel spectral detection. A monosignet CD is seen for the bpy− ππ* absorption centered near 370 nm. A bisignet CD is seen for the bpy ππ* absorption centered near 300 nm. The positions and magnitudes of these CDs can be understood by comparing them with the CDs of (Δ)-Ru(bpy)3+/2+/3+. The CD of the MLCT state is consistent with the description of the state as Ru(III)(bpy)2(bpy−)2+, with a significant amount of coupling between the bpy and bpy−." @default.
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• W2015431489 date "1988-02-01" @default.
• W2015431489 modified "2023-09-26" @default.
• W2015431489 title "Time-resolved circular dichroism of the lowest excited state of (Δ)-Ru(bpy)32+" @default.
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• W2015431489 doi "https://doi.org/10.1016/0009-2614(88)87152-5" @default.
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