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- W2015436447 abstract "The surface tension of binary solutions of benzene, cyclohexane, and dioxane has been studied over the temperature range of 20 to 45°C. The data have been analyzed on the basis of Hoar and Melford [Trans. Faraday Soc.53, 315 (1957)] and Sprow and Prausnitz [Trans. Faraday Soc.62, 1105 (1966)] models; a satisfactory agreement between theory and experimental data has been found. However, while the dW1dT has the right sign for cyclohexane + benzene solutions, it has a sign for cyclohexane + dioxane system opposite to what is expected on the basis of the regular solution theory. The excess surface entropies have been estimated for these systems based on the change of log fiσ with temperature. In the case of benzene + cyclohexane, and to a smaller extent from benzene + dioxane, a possible surface zone structure exists in this temperature interval. In the case of cyclohexane + dioxane this does not occur. This has been related to the geometry of these molecules and their mixing characteristics." @default.
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- W2015436447 date "1980-07-01" @default.
- W2015436447 modified "2023-09-26" @default.
- W2015436447 title "Surface tension and analysis of surface phase of binary solutions of cyclohexane, benzene, and dioxane (20–45°C)" @default.
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- W2015436447 doi "https://doi.org/10.1016/0021-9797(80)90282-9" @default.
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