Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015438096> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2015438096 endingPage "621" @default.
- W2015438096 startingPage "615" @default.
- W2015438096 abstract "The Hofmann rearrangement is an excellent synthetic method to introduce amino functions into aromatic molecules; however, it becomes less efficient in electron-deficient systems because of competitive hydrolytic reactions. This report describes the preparation of the aminodinitrotoluenes (ADNTs) 2-(15N)-amino-4,6-dinitrotoluene and 4-(15N)-amino-2,6-dinitrotoluene by developing conditions using HPLC as a reaction monitoring technique. Both ADNTs were prepared in >70% yield and >95% isotropic purity by using organic solvents and controlling pH during the formation of N-chlorobenzamides and then performing the rearrangement. © 1998 John Wiley & Sons, Ltd." @default.
- W2015438096 created "2016-06-24" @default.
- W2015438096 creator A5017740422 @default.
- W2015438096 creator A5081014443 @default.
- W2015438096 date "1998-07-01" @default.
- W2015438096 modified "2023-10-16" @default.
- W2015438096 title "A reevaluation of the Hofmann rearrangement in electron deficient systems: preparation of 2-(15N)-amino-4,6-dinitrotoluene and 4-(15N)-amino-2,6-dinitrotoluene" @default.
- W2015438096 cites W1975736871 @default.
- W2015438096 cites W2012124756 @default.
- W2015438096 cites W2059304348 @default.
- W2015438096 doi "https://doi.org/10.1002/(sici)1099-1344(199807)41:7<615::aid-jlcr106>3.0.co;2-b" @default.
- W2015438096 hasPublicationYear "1998" @default.
- W2015438096 type Work @default.
- W2015438096 sameAs 2015438096 @default.
- W2015438096 citedByCount "5" @default.
- W2015438096 countsByYear W20154380962015 @default.
- W2015438096 countsByYear W20154380962023 @default.
- W2015438096 crossrefType "journal-article" @default.
- W2015438096 hasAuthorship W2015438096A5017740422 @default.
- W2015438096 hasAuthorship W2015438096A5081014443 @default.
- W2015438096 hasConcept C134121241 @default.
- W2015438096 hasConcept C155647269 @default.
- W2015438096 hasConcept C178790620 @default.
- W2015438096 hasConcept C179998833 @default.
- W2015438096 hasConcept C185592680 @default.
- W2015438096 hasConcept C191897082 @default.
- W2015438096 hasConcept C192562407 @default.
- W2015438096 hasConcept C32909587 @default.
- W2015438096 hasConcept C515207424 @default.
- W2015438096 hasConcept C55493867 @default.
- W2015438096 hasConcept C94412978 @default.
- W2015438096 hasConceptScore W2015438096C134121241 @default.
- W2015438096 hasConceptScore W2015438096C155647269 @default.
- W2015438096 hasConceptScore W2015438096C178790620 @default.
- W2015438096 hasConceptScore W2015438096C179998833 @default.
- W2015438096 hasConceptScore W2015438096C185592680 @default.
- W2015438096 hasConceptScore W2015438096C191897082 @default.
- W2015438096 hasConceptScore W2015438096C192562407 @default.
- W2015438096 hasConceptScore W2015438096C32909587 @default.
- W2015438096 hasConceptScore W2015438096C515207424 @default.
- W2015438096 hasConceptScore W2015438096C55493867 @default.
- W2015438096 hasConceptScore W2015438096C94412978 @default.
- W2015438096 hasIssue "7" @default.
- W2015438096 hasLocation W20154380961 @default.
- W2015438096 hasOpenAccess W2015438096 @default.
- W2015438096 hasPrimaryLocation W20154380961 @default.
- W2015438096 hasRelatedWork W1970144168 @default.
- W2015438096 hasRelatedWork W2047888616 @default.
- W2015438096 hasRelatedWork W2095581038 @default.
- W2015438096 hasRelatedWork W2097014657 @default.
- W2015438096 hasRelatedWork W2326430580 @default.
- W2015438096 hasRelatedWork W2401463829 @default.
- W2015438096 hasRelatedWork W2403182174 @default.
- W2015438096 hasRelatedWork W2949184651 @default.
- W2015438096 hasRelatedWork W2949500570 @default.
- W2015438096 hasRelatedWork W2952649848 @default.
- W2015438096 hasVolume "41" @default.
- W2015438096 isParatext "false" @default.
- W2015438096 isRetracted "false" @default.
- W2015438096 magId "2015438096" @default.
- W2015438096 workType "article" @default.