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- W2015438926 abstract "The structure of the hard sphere dipolar liquid and the electrolyte with added hard sphere ions near a charged hard planar electrode has been investigated with the reference hypernetted chain integral equation (RHNC). We find a decrease of the dielectric function ε near the wall, a decrease of ε in the fluid due to saturation, a field dependent change in the dipole density near the wall, and a decrease of the ion density near the electrode due to solvation. Related to the demixing instability of the ion-dipole mixture, the ions suddenly concentrate near the surface at higher fields and lead to a sharp increase in the differential capacitance. Also electrostriction in the pure dipolar liquid with a field in the bulk is considered." @default.
- W2015438926 created "2016-06-24" @default.
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- W2015438926 date "1995-06-08" @default.
- W2015438926 modified "2023-10-17" @default.
- W2015438926 title "The density and polarization of an ion‐dipole‐electrolyte near a charged wall" @default.
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- W2015438926 doi "https://doi.org/10.1063/1.468849" @default.
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