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- W2015441493 abstract "Abstract The distribution of monooctyl α-anilinobenzylphosphonate (MOABP) and monooctyl α-(2-carboxyanilino) benzylphosphonate(MOCABP) between organic solvents and aqueous chloride and perchlorate solutions of constant ionic strength was studied using 3 P -labelled compounds. The variation of the net distribution ratio ( D R ) with the initial concentration of the extractants in the organic phase was utilized to calculate their distribution constants ( K d ) and dimerization constants ( K 2 ). The D R of MOABP was measured between petroleum ether, cyclohexane, benzene, CCl 4 or CHCl 3 and 0·1 M (H, Na)Cl or (H, Na)ClO 4 solutions. The K d and K 2 constants of MOABP dissolved in CHCl 3 , benzene or cyclohexane were also determined. The D R , K d and K 2 values of MOCABP were determined in the system chloroform 0·1 M and 1 M (H, Na)Cl or (H, Na)ClO 4 solution. The effect of the solvents on the extraction efficiency is demonstrated in the extraction of europium and is discussed in terms of the measured D R values." @default.
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- W2015441493 date "1973-03-01" @default.
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- W2015441493 title "Distribution and dimerization of organophosphorus extractants and their extraction efficiency in different solvents" @default.
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- W2015441493 doi "https://doi.org/10.1016/0022-1902(73)80470-1" @default.
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