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- W2015441629 endingPage "1245" @default.
- W2015441629 startingPage "1245" @default.
- W2015441629 abstract "Solvatochromic data have been collected from the literature or newly measured for 83 molecular solvents, 18 switchable solvents, and 187 ionic liquids that have been cited in the green chemistry literature. The data include the normalized Reichardt's parameter (ENT), the Nile red λmax, and the Kamlet–Taft parameters (α, β, and π*). Disagreements within the literature about the properties of glycerol and poly(ethylene glycol) have been resolved with new data. The switching of a switchable-polarity solvent (also known as a reversible ionic liquid) by CO2 causes a significant increase in polarity/polarizability (π*) but no change in the basicity (β). A switchable-hydrophilicity solvent undergoes an even greater change in polarity because it merges with an aqueous phase upon exposure to CO2. Trends observed from the data of ionic liquids are presented, along with concerns about the best method for determining the Kamlet–Taft parameters." @default.
- W2015441629 created "2016-06-24" @default.
- W2015441629 creator A5018957349 @default.
- W2015441629 creator A5041990892 @default.
- W2015441629 creator A5044309195 @default.
- W2015441629 creator A5062748695 @default.
- W2015441629 date "2012-01-01" @default.
- W2015441629 modified "2023-10-16" @default.
- W2015441629 title "Solvatochromic parameters for solvents of interest in green chemistry" @default.
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