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- W2015452877 abstract "Asymmetric eight-step syntheses are reported for the ent-Corey lactone alcohol derivatives 3a–d and their epimers 4a–d and 14a, b from (R)-2,3-isopropylidene glyceraldehyde (5) as the starting material. The key step of the synthesis is the free radical cyclization of the butenolide thiocarbonates 11, 12 and 13. This reaction produces 3 and 4 in ratios between 57:43 and 30:70 from 11 and 12, whereas 14a and 14b are generated from 13 in a ratio of 19:81. From 3d the prostanoid enone 18 is prepared via the configurationally stable aldehyde 17." @default.
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- W2015452877 title "Asymmetric Synthesis ofent-Corey Lactone Alcohol and its 12-(all-cis)- and 11-Epimers via Free Radical 5-exo-trig-C, C Cyclization" @default.
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- W2015452877 doi "https://doi.org/10.1002/jlac.199419940602" @default.
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