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- W2015455370 abstract "Abstract The synthesis and spectroscopic and magnetic properties of a series of polynuclear metal coordination compounds are described. The compounds have the general formula MX 2 (mtpH) 2 (with M=Mn, Fe, Co, Ni, Cu and Cd; X=Cl, Br; mtpH=5-methyl[1,2,4]triazolo[1,5- a ]pyrimidin-7-ol). The IR spectra and X-ray powder-diffraction patterns indicate the presence of two structure types within the series. On the basis of their ligand-field spectra and magnetic properties a pseudo-octahedral halide-bridged linear-chain structure is derived for most of the compounds. In this structure the metal ions are surrounded by four bridging anions and two N-coordinated, mtpH ligands. Structural exceptions are MnBr 2 (mtpH) 2 and CoBr 2 (mtpH) 2 . These compounds have a different, possibly five-coordinated, structure in which both N and O atoms of mtpH have interactions with the metal ions and/or hydrogen bonding systems." @default.
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- W2015455370 date "1991-02-01" @default.
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- W2015455370 title "Coordination compounds of 5-methyl[1,2,4]triazolo[1,5-a]pyrimidin-7-ol and transition metal(II) halides. Synthesis, spectral and magnetic properties" @default.
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- W2015455370 doi "https://doi.org/10.1016/s0020-1693(00)83061-3" @default.
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