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• W2015456151 abstract "Methane activation by group 5 transition-metal atoms in excess argon and the matrix infrared spectra of reaction products have been investigated. Vanadium forms only the monohydrido methyl complex (CH3−VH) in reaction with CH4 and upon irradiation. On the other hand, the heavier metals form methyl hydride and methylidene dihydride complexes (CH3−MH and CH2MH2) along with the methylidyne trihydride anion complexes (CH⋮MH3-). The neutral products, particularly the methylidene complex, increase markedly on irradiation whereas the anionic product depletes upon UV irradiation or addition of a trace of CCl4 or CBr4 to trap electrons. Other absorptions that emerge on irradiation and annealing increase markedly at higher precursor concentration and are attributed to a higher-order product ((CH3)2MH2)). Spectroscopic evidence suggests that the agostic Nb and Ta methylidene dihydride complexes have two identical metal−hydrogen bonds." @default.
• W2015456151 created "2016-06-24" @default.
• W2015456151 creator A5029634322 @default.
• W2015456151 creator A5036641250 @default.
• W2015456151 date "2006-02-28" @default.
• W2015456151 modified "2023-10-18" @default.
• W2015456151 title "Methane Activation by Laser-Ablated V, Nb, and Ta Atoms: Formation of CH₃−MH, CH₂MH₂, CH⋮MH₃^-, and (CH₃)₂MH₂" @default.
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• W2015456151 doi "https://doi.org/10.1021/jp057029f" @default.
• W2015456151 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16539410" @default.
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