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- W2015457891 abstract "Abstract The reactions of [RhRu3(μH)2(μCO)(CO)9(μ5C5H5)] with triphenylphosphine and trimethylphosphite and of [RhRu3(μH)2(μCO)(CO)9(μ5C5Me5)] with triphenylphosphine yield clusters [RhRu3(μH)2(μCO)(CO)9−n(PR3)nCp′] (n = 1, 2; R = Ph, Cp′ = μ5C5H5, μ5C5Me5 and R = OME, Cp′ = μ5C5H5) and cleavage products. The structures and isomerisation of the phosphorus containing clusters have been investigated by 1H and 31P NMR spectroscopy. The crystal structure of [RhRu3(μH)2(μCO)(CO)7(PPh3)2(μ5C5H5)] has been determined by X-ray diffraction, and the molecule is shown to contain PPh3 ligands bonded axially and equatorially to two basal ruthenium atoms." @default.
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- W2015457891 date "1991-08-01" @default.
- W2015457891 modified "2023-09-27" @default.
- W2015457891 title "Tetranuclear rhodium-triruthenium carbonyl clusters containing phosphorus(III) ligands; crystal and molecular structure of [RhRu3(μ-H)2(μ-CO)(CO)7(PPh3)2(μ5-C5H5)]" @default.
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- W2015457891 doi "https://doi.org/10.1016/0022-328x(91)80061-n" @default.
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