FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015459067> ?p ?o ?g. }

• W2015459067 endingPage "443" @default.
• W2015459067 startingPage "443" @default.
• W2015459067 abstract "Synthetic and structural studies have been made for a range of cationic, ten-electron, four-co-ordinate, diarylbis(ligand)bismuth(III) complexes. Reactions between BiPh2Br, AgBF4 and 2 equivalents of a two-electron donor ligand L afforded the ionic complexes [BiPh2L2][BF4][L = OPPh3 or pyridine (py)]. The first was characterised by X-ray crystallography and comprises [BiPh2(OPPh3)2]+ cations, tetrafluoroborate anions and CH2Cl2 molecules of crystallisation. The bismuth centre is four-co-ordinate with a disphenoidal geometry in which the aryl groups are in equatorial positions with the ligands in axial sites. A long interaction is present between the bismuth centre and one of the fluorines of the BF4 group. A series of similar reactions were also carried out between BiR2Br (R = aryl), TlPF6 and 2 equivalents of L affording the ionic complexes [BiR2L2][PF6][R = Ph, L = OP(NMe2)3 or py; R = 4-MeC6H4, L = OP(NMe2)3; R = 2,4,6-Me3C6H2, L = OP(NMe2)3 or OPPh3]. Two of the complexes have also been characterised by X-ray crystallography, the cations having similar structures to that found in [BiPh2(OPPh3)2][BF4]. The reaction between BiPhBr2, 1 equivalent of TlPF6 and an excess of OP(NMe2)3 afforded the ionic complex [BiPh{OP(NMe2)3}4][PF6]2. The crystal structure of the dication comprises a square-based pyramidal bismuth centre with an apical phenyl group and four basal OP(NMe2)3 ligands. Examples of some dihalogenobismuth cations have also been obtained and their structures are described and compared with those of previously reported examples." @default.
• W2015459067 created "2016-06-24" @default.
• W2015459067 creator A5051177319 @default.
• W2015459067 creator A5075897059 @default.
• W2015459067 creator A5083617813 @default.
• W2015459067 date "1996-01-01" @default.
• W2015459067 modified "2023-10-03" @default.
• W2015459067 title "Cationic, arylbismuth(III) complexes of the form [BiR2L2]+ and [BiRL4]2+ where L is a neutral two-electron donor ligand" @default.
• W2015459067 cites W125958654 @default.
• W2015459067 cites W1503360834 @default.
• W2015459067 cites W1972608817 @default.
• W2015459067 cites W1973812288 @default.
• W2015459067 cites W1976217112 @default.
• W2015459067 cites W2005603297 @default.
• W2015459067 cites W2014845950 @default.
• W2015459067 cites W2019971348 @default.
• W2015459067 cites W2023591548 @default.
• W2015459067 cites W2042215321 @default.
• W2015459067 cites W2052184080 @default.
• W2015459067 cites W2053116621 @default.
• W2015459067 cites W2063109436 @default.
• W2015459067 cites W2064068872 @default.
• W2015459067 cites W2064917729 @default.
• W2015459067 cites W2071964146 @default.
• W2015459067 cites W2076293245 @default.
• W2015459067 cites W2085709283 @default.
• W2015459067 cites W2101748147 @default.
• W2015459067 cites W2137186255 @default.
• W2015459067 cites W2334025688 @default.
• W2015459067 cites W2344889448 @default.
• W2015459067 cites W2956122686 @default.
• W2015459067 doi "https://doi.org/10.1039/dt9960000443" @default.
• W2015459067 hasPublicationYear "1996" @default.
• W2015459067 type Work @default.
• W2015459067 sameAs 2015459067 @default.
• W2015459067 citedByCount "51" @default.
• W2015459067 countsByYear W20154590672012 @default.
• W2015459067 countsByYear W20154590672013 @default.
• W2015459067 countsByYear W20154590672014 @default.
• W2015459067 countsByYear W20154590672016 @default.
• W2015459067 countsByYear W20154590672017 @default.
• W2015459067 countsByYear W20154590672018 @default.
• W2015459067 countsByYear W20154590672019 @default.
• W2015459067 countsByYear W20154590672020 @default.
• W2015459067 countsByYear W20154590672021 @default.
• W2015459067 countsByYear W20154590672022 @default.
• W2015459067 countsByYear W20154590672023 @default.
• W2015459067 crossrefType "journal-article" @default.
• W2015459067 hasAuthorship W2015459067A5051177319 @default.
• W2015459067 hasAuthorship W2015459067A5075897059 @default.
• W2015459067 hasAuthorship W2015459067A5083617813 @default.
• W2015459067 hasConcept C115624301 @default.
• W2015459067 hasConcept C116569031 @default.
• W2015459067 hasConcept C145148216 @default.
• W2015459067 hasConcept C154881586 @default.
• W2015459067 hasConcept C155647269 @default.
• W2015459067 hasConcept C161790260 @default.
• W2015459067 hasConcept C170493617 @default.
• W2015459067 hasConcept C178790620 @default.
• W2015459067 hasConcept C183882617 @default.
• W2015459067 hasConcept C185592680 @default.
• W2015459067 hasConcept C2182769 @default.
• W2015459067 hasConcept C2779485729 @default.
• W2015459067 hasConcept C2780263894 @default.
• W2015459067 hasConcept C2780872544 @default.
• W2015459067 hasConcept C2781076698 @default.
• W2015459067 hasConcept C32909587 @default.
• W2015459067 hasConcept C533668322 @default.
• W2015459067 hasConcept C55493867 @default.
• W2015459067 hasConcept C66009135 @default.
• W2015459067 hasConcept C71240020 @default.
• W2015459067 hasConcept C8010536 @default.
• W2015459067 hasConceptScore W2015459067C115624301 @default.
• W2015459067 hasConceptScore W2015459067C116569031 @default.
• W2015459067 hasConceptScore W2015459067C145148216 @default.
• W2015459067 hasConceptScore W2015459067C154881586 @default.
• W2015459067 hasConceptScore W2015459067C155647269 @default.
• W2015459067 hasConceptScore W2015459067C161790260 @default.
• W2015459067 hasConceptScore W2015459067C170493617 @default.
• W2015459067 hasConceptScore W2015459067C178790620 @default.
• W2015459067 hasConceptScore W2015459067C183882617 @default.
• W2015459067 hasConceptScore W2015459067C185592680 @default.
• W2015459067 hasConceptScore W2015459067C2182769 @default.
• W2015459067 hasConceptScore W2015459067C2779485729 @default.
• W2015459067 hasConceptScore W2015459067C2780263894 @default.
• W2015459067 hasConceptScore W2015459067C2780872544 @default.
• W2015459067 hasConceptScore W2015459067C2781076698 @default.
• W2015459067 hasConceptScore W2015459067C32909587 @default.
• W2015459067 hasConceptScore W2015459067C533668322 @default.
• W2015459067 hasConceptScore W2015459067C55493867 @default.
• W2015459067 hasConceptScore W2015459067C66009135 @default.
• W2015459067 hasConceptScore W2015459067C71240020 @default.
• W2015459067 hasConceptScore W2015459067C8010536 @default.
• W2015459067 hasIssue "4" @default.
• W2015459067 hasLocation W20154590671 @default.
• W2015459067 hasOpenAccess W2015459067 @default.
• W2015459067 hasPrimaryLocation W20154590671 @default.
• W2015459067 hasRelatedWork W1977537854 @default.

• next