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- W2015465564 abstract "Novel isothermal (P–x–y) vapour–liquid equilibrium data are reported at three temperatures for each of the (1,1,2,3,3,3-hexafluoro-1-propene + 1-butene), (2,2,3-trifluoro-3-(trifluoromethyl)oxirane + 1-butene), and (difluoromethane + 1-butene) binary systems. The experimental values were measured on a “static–analytic” type apparatus which utilized two electromagnetic ROLSITM capillary samplers for repeatable and reliable equilibrium phase sampling and handling. The VLE results are correlated with in-house thermodynamic software based on the “PR–MC–WS–NRTL” model which comprises the Mathias–Copeman alpha function, Wong–Sandler mixing rule, and non-random two-liquid local composition activity model introduced in the Peng–Robinson equation of state. A maximum pressure azeotrope is observed at all temperatures studied for the (2,2,3-trifluoro-3-(trifluoromethyl)oxirane + 1-butene), and (difluoromethane + 1-butene systems), but not for the 1,1,2,3,3,3-hexafluoro-1-propene system. Liquid–liquid immiscibility is not observed for any of the systems studied over the range of temperatures investigated." @default.
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- W2015465564 date "2013-06-01" @default.
- W2015465564 modified "2023-09-27" @default.
- W2015465564 title "Experimental vapour–liquid equilibrium data and modeling for binary mixtures of 1-butene with 1,1,2,3,3,3-hexafluoro-1-propene, 2,2,3-trifluoro-3-(trifluoromethyl)oxirane, or difluoromethane" @default.
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- W2015465564 doi "https://doi.org/10.1016/j.jct.2013.01.017" @default.
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