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- W2015470080 abstract "Substitution of surface -OH groups of TiO2 may influence competition between photoinduced energy and electron-transfer processes and lead to improved singlet oxygen generation. In contrast to neat TiO2, surface modified titanium dioxide can photocatalyze degradation of a very stable substance, cyanuric acid. Presented results are in contradiction to usually accepted hypothesis of the mechanism of cyanuric acid photodegradation in the presence of fluorinated TiO2 (F-TiO2) in which bulk hydroxyl radicals play a key role. It seems plausible that the difference of activity observed for TiO2 and F-TiO2 is not related to various types of generated hydroxyl radicals, but rather to competition between electron-transfer processes (formation of radicals) and energy-transfer processes (formation of singlet oxygen)." @default.
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- W2015470080 date "2006-11-16" @default.
- W2015470080 modified "2023-09-27" @default.
- W2015470080 title "Singlet Oxygen Photogeneration at Surface Modified Titanium Dioxide" @default.
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- W2015470080 doi "https://doi.org/10.1021/ja065970m" @default.
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