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- W2015474193 abstract "The changes of properties of an achiral prosthetic group upon its fixation on the chiral molecular matrix are discussed using the concept of chirality. We analyze the difference Δ〈A〉 = 〈A〉R − 〈A〉L in the expectation values of an operator describing the change of the prosthetic group property when it is bonded in two orientations, enatiomorphous with respect to the chiral molecular matrix. The wavefunctions of Barron and a density matrix formalism are used to show that Δ〈A〉 is nonzero for both parity odd and even observables, thus distinguishing molecular complexes from enantiomeric species. The examples demonstrate the interconnection of Δ〈A〉 with the energetics of interaction between the matrix and the prosthetic group." @default.
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- W2015474193 date "1992-04-01" @default.
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- W2015474193 title "Chirality of ordered molecular complexes consisting of protein with fixed prosthetic group" @default.
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- W2015474193 doi "https://doi.org/10.1016/0009-2614(92)85596-3" @default.
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