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- W2015477064 abstract "A new class of imide- and urea-based hetero-strands with a quadruple ADDA/DAAD hydrogen-bond array was designed and synthesized from easily accessible starting materials. The molecular recognition between the two different strands depends highly on the substituents and the linker between neighboring hydrogen-bonds, which results in the stability of these heteroduplexes varying from 103 to >105 M−1 in apolar solvents. In particular, an increase of the association constant by up to one order of magnitude was observed by derivatizing the ADDA arrays at the termini with electron-withdrawing groups. Molecular modelling of the representative complementary complexes reveals the binding mode of four hydrogen-bond arrays that agrees with the matched pair." @default.
- W2015477064 created "2016-06-24" @default.
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- W2015477064 date "2013-01-01" @default.
- W2015477064 modified "2023-10-16" @default.
- W2015477064 title "Quadruply hydrogen-bonded heteroduplexes based on imide and urea units arrayed with ADDA/DAAD sequences" @default.
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- W2015477064 doi "https://doi.org/10.1039/c3ob40998h" @default.
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