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• W2015536699 abstract "From the circular dichroisrm spectra of 23 aldoses and 10 ketoses in aqueous solution, a symmetry rule was derived relating the sign of the n- band of the carbonyl form to the absolute configuration of the sugar. The sign is positive when the configuration of the adjacent chiral center is (S), and it is negative when the configuration is (R). The rule also holds for aldehydo- and keto-sugar peracetates, and for y-lactones substituted with oxygen-containing groups. The magnitude of a mean, molar, dichroic-extinction coefficient for the pure carbonyl forms of aldoses and ketoses was estimated from published c.d. data on the aldehydo- and keto-sugar peracetates and related compounds, which permitted estimation of the proportion of the carbonyl form in the equilibrium mixture for each sugar. D-Glucose had the smallest carbonyl concentration, 0.002% at 20°, in agreement with an earlier, polarographic value. The relationship between carbonyl content and sugar structure and configuration is discussed." @default.
• W2015536699 created "2016-06-24" @default.
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• W2015536699 date "1977-01-01" @default.
• W2015536699 modified "2023-10-18" @default.
• W2015536699 title "A Symmetry rule for the Circular Dichroism of reducing sugars, and the proportion of Carbonyl forms in Aqueous solutions thereof" @default.
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• W2015536699 doi "https://doi.org/10.1016/s0008-6215(00)85450-6" @default.
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