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• W2015540211 abstract "Abstract The Mossbauer hyperfine spectra of the 60 keV resonance of 237 Np in powder and single crystal absorbers of NpAs 2 were measured between 4.2 and 60 K. Below 18 K a simple magnetic plus quadrupole pattern is seen in accordance with a ferromagnetic spin structure in tetragonal NpAs 2 . The isomer shift favors the 4+ charge state, the hyperfine field of 288 T implies a moment of 1.5μ B at the Np ion. The large reduction compared to the free ion values points towards a strong mixing of the electronic ground state by crystalline field interactions. Above 18 K the spectrum changes into a complex hyperfine pattern indicating a sinusoidally modulated spin structure. Near 54 K a transition into the paramagnetic state is observed. Both magnetic transitions (18 and 54 K) exhibit a feature typical for a first-order character." @default.
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• W2015540211 date "1982-11-01" @default.
• W2015540211 modified "2023-10-08" @default.
• W2015540211 title "Magnetic behaviour of NpAs2 from Mössbauer spectroscopy" @default.
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• W2015540211 doi "https://doi.org/10.1016/0304-8853(82)90019-1" @default.
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