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• W2015566207 abstract "A pulsed-laser photolysis/laser-induced fluorescence technique is employed in the determination of the pressure and temperature dependence of the reaction of CN with NO in the range from 207 to 740 K and for Ar bath gas pressures ranging from 30 to 900 Torr. A variational RRKM model coupled with a one-dimensional master equation treatment provides a reasonably satisfactory description of the available kinetic data for both the association and dissociation processes. The association kinetic data is best fit by a collisional energy transfer parameter, 〈ΔE〉down, for the simple exponential down model, which gradually increases from −35 cm-1 at 100 K to −500 cm-1 at 740 K. The expression 3.4 × 10-10 exp(120/T) cm3 s-1 reproduces the present theoretical estimates for the high-pressure rate constant in the range from 207 to 740 K." @default.
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• W2015566207 date "1998-08-01" @default.
• W2015566207 modified "2023-10-17" @default.
• W2015566207 title "A Theoretical and Experimental Study of the CN + NO Association Reaction" @default.
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• W2015566207 doi "https://doi.org/10.1021/jp981946m" @default.
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