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- W2015572904 abstract "1-Chloro-1-phenylethyl-telechelic polyisobutylene (PIB) was synthesized by living carbocationic polymerization (LCCP). LCCP of isobutylene was induced by a difunctional initiator in conjunction with TiCl4 as coinitiator in the presence of N,N-dimethylacetamide in CH2Cl2/hexane (40:60 v/v) solvent mixture at −78°C. After complete isobutylene conversion a small amount of styrene was added leading to a rapid crossover reaction and thus to the attachment of short outer polystyrene (PSt) blocks to the PIB segment. Quenching the living polymerization of styrene yielded 1-chloro-1-phenylethyl terminal groups. The resulting telechelic polymer (Cl-PSt-PIB-PSt-Cl) is a potential new macroinitiator for atom transfer radical polymerization of a variety of vinyl monomers." @default.
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- W2015572904 date "1998-01-01" @default.
- W2015572904 modified "2023-10-18" @default.
- W2015572904 title "Synthesis of 1-chloro-1-phenylethyl-telechelic polyisobutylene, a new potential macroinitiator by living cationic polymerization" @default.
- W2015572904 doi "https://doi.org/10.1002/(sici)1521-3927(19980101)19:1<15::aid-marc15>3.0.co;2-7" @default.
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