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- W2015583855 abstract "This brief account discusses the development of HCl/TiCl4-n(OR)n (n = 1–4), the titanium-based new initiating systems for living cationic polymerizations of vinyl ethers and styrene. The focus of this development is controlling the Lewis acidity of the metal halide components [TiCl4-n(OR)n] or “activators” in relation to the structure of the monomers. Thus, for vinyl ethers, relatively mild Lewis acids such as TiCl(OiPr)3 and TiCl2(OiPr)2 are effective, whereas for styrene, a stronger Lewis acid such as TiCl3(OiPr) is employed along with an added salt (nBu4N+Cl−). In both cases, living polymers of controlled molecular weights can be obtained in methylene chloride solvent at −15°C." @default.
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- W2015583855 date "1995-07-01" @default.
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- W2015583855 title "Titanium-based lewis acids for living cationic polymerizations of vinyl ethers and styrene: Control of lewis acidity in design of initiating systems" @default.
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- W2015583855 doi "https://doi.org/10.1002/masy.19950980112" @default.
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