Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015584908> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2015584908 endingPage "3123" @default.
- W2015584908 startingPage "3115" @default.
- W2015584908 abstract "Hexaplatinum cluster complexes have been prepared by reduction of [PtCl2(SMe2)2] with NaBH4 in the presence of CO and the diphosphine ligands Ph2P(CH2)nPPh2, n = 2 (dppe), 3 (dppp), 4 (dppb), 5 (dpppe), and 6 (dpph). The products are the closed cluster [Pt6(μ-CO)6(μ-dppe)3], 2b, and the open cluster [Pt6(μ-CO)6(μ-dppp)2(dppp)2], 9, but the reactions failed to give isolable products when n = 4−6. Cluster 9 can encapsulate mercury(0) or thallium(I) with loss of dppp to give the closed clusters [Pt6(μ6-Hg)(μ-CO)6(μ-dppp)3], 10a, or [Pt6(μ6-Tl)(μ-CO)6(μ-dppp)3]+, 11a, respectively. The Pt6(μ-CO)6(μ-dppp)3 unit acts as a cryptand and evidence is presented that the cluster 10a must open to allow reaction with thallium(I) to give 11a. Reduction of [PtCl2(SMe2)2] with NaBH4 in the presence of CO, the diphosphine ligands Ph2P(CH2)nPPh2, and mercury can give [Pt6(μ6-Hg)(μ-CO)6{μ-Ph2P(CH2)nPPh2}3], 10a−d, n = 3−6, respectively, directly, but clusters [Pt6(μ6-Hg)(μ-CO)6(CO)2{μ-Ph2P(CH2)nPPh2}2], 12, are also formed in some cases. Cluster 2b reacts with [Ph3PAu]+ to give [Pt6(μ-CO)6(μ-dppe)3(μ3-AuPPh3)2]2+." @default.
- W2015584908 created "2016-06-24" @default.
- W2015584908 creator A5021402070 @default.
- W2015584908 creator A5033575784 @default.
- W2015584908 creator A5053787597 @default.
- W2015584908 date "1996-07-09" @default.
- W2015584908 modified "2023-10-16" @default.
- W2015584908 title "Hexaplatinum Clusters with Carbonyl and Diphosphine Ligands and the Trapping of Mercury(0) and Thallium(I)" @default.
- W2015584908 cites W1964010583 @default.
- W2015584908 cites W1973706646 @default.
- W2015584908 cites W1982328194 @default.
- W2015584908 cites W1990447826 @default.
- W2015584908 cites W1995260000 @default.
- W2015584908 cites W2000077027 @default.
- W2015584908 cites W2002217651 @default.
- W2015584908 cites W2018903306 @default.
- W2015584908 cites W2036585675 @default.
- W2015584908 cites W2041434485 @default.
- W2015584908 cites W2044323894 @default.
- W2015584908 cites W2044505028 @default.
- W2015584908 cites W2048030075 @default.
- W2015584908 cites W2052282170 @default.
- W2015584908 cites W2076155990 @default.
- W2015584908 cites W2077258884 @default.
- W2015584908 cites W2090075038 @default.
- W2015584908 cites W2094881197 @default.
- W2015584908 cites W2101479143 @default.
- W2015584908 cites W3004442540 @default.
- W2015584908 cites W314267765 @default.
- W2015584908 doi "https://doi.org/10.1021/om960148k" @default.
- W2015584908 hasPublicationYear "1996" @default.
- W2015584908 type Work @default.
- W2015584908 sameAs 2015584908 @default.
- W2015584908 citedByCount "34" @default.
- W2015584908 countsByYear W20155849082012 @default.
- W2015584908 countsByYear W20155849082019 @default.
- W2015584908 countsByYear W20155849082022 @default.
- W2015584908 crossrefType "journal-article" @default.
- W2015584908 hasAuthorship W2015584908A5021402070 @default.
- W2015584908 hasAuthorship W2015584908A5033575784 @default.
- W2015584908 hasAuthorship W2015584908A5053787597 @default.
- W2015584908 hasConcept C155647269 @default.
- W2015584908 hasConcept C161790260 @default.
- W2015584908 hasConcept C164866538 @default.
- W2015584908 hasConcept C178790620 @default.
- W2015584908 hasConcept C179104552 @default.
- W2015584908 hasConcept C185592680 @default.
- W2015584908 hasConcept C18903297 @default.
- W2015584908 hasConcept C199360897 @default.
- W2015584908 hasConcept C2777164566 @default.
- W2015584908 hasConcept C2777777548 @default.
- W2015584908 hasConcept C2777924906 @default.
- W2015584908 hasConcept C2780696404 @default.
- W2015584908 hasConcept C41008148 @default.
- W2015584908 hasConcept C559099789 @default.
- W2015584908 hasConcept C71240020 @default.
- W2015584908 hasConcept C8010536 @default.
- W2015584908 hasConcept C86803240 @default.
- W2015584908 hasConceptScore W2015584908C155647269 @default.
- W2015584908 hasConceptScore W2015584908C161790260 @default.
- W2015584908 hasConceptScore W2015584908C164866538 @default.
- W2015584908 hasConceptScore W2015584908C178790620 @default.
- W2015584908 hasConceptScore W2015584908C179104552 @default.
- W2015584908 hasConceptScore W2015584908C185592680 @default.
- W2015584908 hasConceptScore W2015584908C18903297 @default.
- W2015584908 hasConceptScore W2015584908C199360897 @default.
- W2015584908 hasConceptScore W2015584908C2777164566 @default.
- W2015584908 hasConceptScore W2015584908C2777777548 @default.
- W2015584908 hasConceptScore W2015584908C2777924906 @default.
- W2015584908 hasConceptScore W2015584908C2780696404 @default.
- W2015584908 hasConceptScore W2015584908C41008148 @default.
- W2015584908 hasConceptScore W2015584908C559099789 @default.
- W2015584908 hasConceptScore W2015584908C71240020 @default.
- W2015584908 hasConceptScore W2015584908C8010536 @default.
- W2015584908 hasConceptScore W2015584908C86803240 @default.
- W2015584908 hasIssue "14" @default.
- W2015584908 hasLocation W20155849081 @default.
- W2015584908 hasOpenAccess W2015584908 @default.
- W2015584908 hasPrimaryLocation W20155849081 @default.
- W2015584908 hasRelatedWork W1977105965 @default.
- W2015584908 hasRelatedWork W2008136765 @default.
- W2015584908 hasRelatedWork W2069105935 @default.
- W2015584908 hasRelatedWork W2151559666 @default.
- W2015584908 hasRelatedWork W2376304445 @default.
- W2015584908 hasRelatedWork W2606325330 @default.
- W2015584908 hasRelatedWork W2951979683 @default.
- W2015584908 hasRelatedWork W2952482325 @default.
- W2015584908 hasRelatedWork W2953135579 @default.
- W2015584908 hasRelatedWork W3109328249 @default.
- W2015584908 hasVolume "15" @default.
- W2015584908 isParatext "false" @default.
- W2015584908 isRetracted "false" @default.
- W2015584908 magId "2015584908" @default.
- W2015584908 workType "article" @default.