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- W2015603493 abstract "The reaction of the tetradentate dicarboxamide ligand 1,2-bis-N-[2′(diphenylphosphanyl)benzoyl]diaminobenzene (dppbH2) with RuCl3 in DMF or ethanol results in metal-mediated ligand oxidation and formation of the diamagnetic Ru(II) complex [(dppQ)Ru(Cl)2] (1) with N2P2 chromophore. The o-phenylenedicarboxamide portion of the dppb2− ligand is oxidized to a o-benzoquinonediimine (bqdi) moiety in [(dppQ)Ru(Cl)2]. Presence of oxygen accelerates the ligand oxidation process. Unlike other tetradentate dicarboxamide ligands with pyridine-N, phenolato-O, or thiolato-S donors, dppb2− provides stability to the +2 oxidation state of ruthenium and facilitates oxidation of the coordinated ligand frame. Results of spectroscopic and redox studies strongly support the +2 oxidation state of Ru in 1. Exposure of 1 to NO(g) does not lead to formation of any metal nitrosyl; instead, the bqdi ring is nitrated to afford [(NO2dppQ)Ru(Cl)2] (2)." @default.
- W2015603493 created "2016-06-24" @default.
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- W2015603493 date "2008-11-12" @default.
- W2015603493 modified "2023-09-30" @default.
- W2015603493 title "Facile Ligand Oxidation and Ring Nitration in Ruthenium Complexes Derived from a Ligand with Dicarboxamide-N and Phosphine-P Donors" @default.
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- W2015603493 doi "https://doi.org/10.1021/ic801243a" @default.
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