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- W2015607958 abstract "A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(II) complexes [e.g., RuCl2(PPh3)3; PhC6H5]. These initiators include chloromethanes, α-chloroesters, α-chloroketones, and α-bromoesters, among which CCl3COCH3, CHCl2COPh, and H(MMA)2-Br are the best to give polymers with controlled molecular weights and very narrow MWDs (MwMn = 1.1−1.2). The wide variation of the initiators therefore demonstrates the generality of our transition metal-mediated living radical polymerizations." @default.
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- W2015607958 title "Design of initiators for living radical polymerization of methyl methacrylate mediated by ruthenium(II) complex" @default.
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- W2015607958 doi "https://doi.org/10.1016/s0040-4020(97)00972-1" @default.
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