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- W2015633420 abstract "Oxovanadium(IV) complexes of the 2-amino-1-cyclopentene-1-dithiocarboxylate (acdc) and 2-methylamino-1-cyclopentene-1-dithiocarboxylate (NCH3acdc) anion have been synthesized and characterized by using IR, EPR, magnetic susceptibility and XPS measurements to elucidate the coordination environment of oxovanadium(IV) complexes of the acdc ligand and its derivative. The corresponding spin-Hamiltonian parameters, 〈g〉 values and hyperfine coupling constants, 〈A〉 have been examined for the prepared complexes having VO(IV)N2S2 and VO(IV)S4 chromophore. The EPR data confirm its usefulness in the characterization of the coordination environments of these compounds. The XPS studies have also provided us with valuable information on the binding properties of VO(acdc)2 and VO(NCH3acdc)2. The magnetic susceptibility, coupled with the VO stretching frequency suggest the presence of some degree of magnetic interaction in these compounds." @default.
- W2015633420 created "2016-06-24" @default.
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- W2015633420 date "2000-10-01" @default.
- W2015633420 modified "2023-10-03" @default.
- W2015633420 title "Magnetic properties and coordination environments of oxovanadium(IV) within VO(IV)N2S2 and VO(IV)S4 chromophores" @default.
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- W2015633420 doi "https://doi.org/10.1016/s0277-5387(00)00528-3" @default.
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