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• W2015646908 abstract "The anionic polymerization of (R)-β-butyrolactone initiated with either 18-crown-6 complexes of a potassium alkoxide or a simple carboxylate (reference initiator) proceeded with inversion of configuration. As a result (R)-β-butyrolactone formed an isotactic poly((S)-β-hydroxybutyrate) with these initiators at room temperature. Polymerization of (R,S)-β-butyrolactone under the same conditions gave an atactic polymer, but at lower temperatures the predominantly syndiotactic form of poly((R,S)-β-hydroxybutyrate) was produced from the racemic monomer." @default.
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• W2015646908 date "1996-01-01" @default.
• W2015646908 modified "2023-10-14" @default.
• W2015646908 title "Stereochemical Control in the Anionic Polymerization of β-Butyrolactone Initiated with Alkali-Metal Alkoxides" @default.
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• W2015646908 doi "https://doi.org/10.1021/ma951888s" @default.
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