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- W2015647637 abstract "The reaction of CF3 radicals with NH3 has been studied over a wide temperature range 298–673 K, using the photolysis and the thermal decomposition of CF3I as the free radical source. It was found that the reaction could not be explained in terms of a simple mechanism in the whole temperature range because a marked pressure dependence on the rate of products formation and the presence of a dark reaction complicate the system at low temperatures. Thus, Arrhenius parameters for reaction (1) have been calculated relative to the CF3 recombination from data in the range 523–673 K where pure hydrogen transfer occurs. The rate constant expression is given by where kH/k is in units of cm3/2/mol1/2 s1/2 and θ = 2.303 RT/kJ/mol." @default.
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- W2015647637 date "1985-11-01" @default.
- W2015647637 modified "2023-10-01" @default.
- W2015647637 title "Arrhenius parameters for the hydrogen abstraction from ammonia by CF3 radicals" @default.
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- W2015647637 doi "https://doi.org/10.1002/kin.550171108" @default.
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