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• W2015649552 abstract "Abstract A chemometric process consisting in measuring the reactivity of a set of substrates under standardized and complementary reaction conditions was run to evaluate the possibility of building a coherent database that would give a general overview of the selectivity of a variety of catalysts. This systematic experimental approach was applied to the hydrogenolysis of O ‐benzyl ether compounds. Analysis of collected data revealed reaction conditions with precise chemoselectivity. For instance, Pd/C in EtOH or PdOH in THF enabled the specific cleavage of the benzyl group in the presence of p ‐CF 3 Bn groups, and addition of triethylamine in EtOH suppressed the cleavage of the phenoxybenzyl bond. The latter selectivity was exemplified on several polyfunctional substrates." @default.
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• W2015649552 date "2010-04-01" @default.
• W2015649552 modified "2023-10-18" @default.
• W2015649552 title "A Chemometric Approach to Map Reaction Media Chemoselectivity: Example of Selective Debenzylation" @default.
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• W2015649552 doi "https://doi.org/10.1002/ejoc.200901497" @default.
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