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• W2015671042 abstract "The excitation function for the formation of HD was determined by means of a nonequilibrium bulb method in the relative energy range of ∼ 0.5–1.7 eV. Hydrogen atoms of various well-known initial kinetic energies, 0.35, 0.48, 0.67, 0.92, 1.15, 1.67, and 2.05 eV, were generated by the photodissociation of HI and HBr in the presence of either n-C4D10 or n-CD3–(CH2)2–CD3. Temperature variation studies performed at the lowest source energy allowed an estimate, 0.35 eV, for the sec-abstraction threshold energy. The excitation function was related to the measured HD yields through an integral equation, derived previously. The cross section rises from threshold to a maximum value (∼ 0.35 Å2) at about 1.2 eV with an energy dependence intermediate between that predicted by the familiar line-of-centers and step function models, and then decreases with increasing energy. The results are compared with other experimental and theoretical studies." @default.
• W2015671042 created "2016-06-24" @default.
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• W2015671042 date "1971-03-15" @default.
• W2015671042 modified "2023-10-17" @default.
• W2015671042 title "Experimental Determination of the Excitation Function for the Reaction: H+<i>n</i>‐C₄D₁₀→HD+C₄D₉(sec)" @default.
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• W2015671042 doi "https://doi.org/10.1063/1.1675180" @default.
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