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- W2015682282 abstract "The calculation of the coupling constants of the magnetic and electric hfs of the NO molecule is done using the Heitler-London wave function with Hartree atomic wave function. The homopolar ground state is found to be expressed by a linear combination of four Slater determinants. This wave function is used with success to calculate the spin-orbit coupling constant and the $ensuremath{Lambda}$-type doublet separation as well as the hfs coupling constants. The $s$-character of the magnetic hfs is explained by the configuration interaction with an excited state of the N atom, in which one of the $2s$-electrons is promoted to the $3s$ orbital. The effective number of the odd electron in the electric hfs is 0.46, and $Q$ for the N nucleus is 0.03ifmmodetimeselsetexttimesfi{}${10}^{ensuremath{-}24}$ ${mathrm{cm}}^{2}$. No ionic structure needs to be considered." @default.
- W2015682282 created "2016-06-24" @default.
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- W2015682282 date "1957-02-15" @default.
- W2015682282 modified "2023-10-14" @default.
- W2015682282 title "Theory of the Hyperfine Structure of NO Molecule. Electronic Structure" @default.
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- W2015682282 doi "https://doi.org/10.1103/physrev.105.1262" @default.
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